The A-list couple braved the freezing cold and wet weather to sign autographs for ecstatic fans outside the Royal Opera House in Covent Garden.
The pair brought a touch of old Hollywood glamour to the damp red carpet with Jolie wearing a strapless, floor-length black dress complete with a two yellow stripes. Color!
A dashing, tuxedo-clad Pitt joked about the dismal weather: 'It's a nice change for us... all that sun!'
Check back tomorrow for all of our BAFTA coverage!
Check out all 35+ photos of Brad Pitt and Angelina Jolie at the BAFTAs in the gallery.
Photo Credit: Getty Images
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Stephen Park says:
floor length?? hhhhmm only if the floor starts mid calf on angie?!
rose says:
The dress isn't floor length retard. if your gonna talk a bunch of shit about people at least get your info right!
Nicky says:
Oh my goodness, someone accidently made a mistake. Shock horror. It's a bit politically incorrect to call some one a retard Rose. Not a nice word to us. People can be so nasty.
LeslieD says:
i love the splash of color but that dress looks horrible on her. The fit and length is all wrong.
ragmaglover says:
There's all this splashy glamor and then, wham, those skinny arms w/tattoos, I don't think I'll ever get use to them. IMHO it ain't right.
Denise Trun says:
I think Angelina looks ugly!I'm a gay broad and i am not that into her! i would prefer Anniston anyday!
Epkqedli says:
kprMDG comment2 ,